N,N-Dimethylethylenediamine → N-(3,7,11,15-Tetramethyl-2,6,10,14-hexadecatetraenoyl)-N',N'-dimethylethylenediamine

HRID 34563

反応式

HRID 34563 の反応式
[CH3:1][C:2]([CH2:7][CH2:8][CH:9]=[C:10]([CH3:22])[CH2:11][CH2:12][CH:13]=[C:14]([CH3:21])[CH2:15][CH2:16][CH:17]=[C:18]([CH3:20])[CH3:19])=[CH:3][C:4]([OH:6])=O.[CH3:23][N:24]([CH3:28])[CH2:25][CH2:26][NH2:27]>>[CH3:1][C:2]([CH2:7][CH2:8][CH:9]=[C:10]([CH3:22])[CH2:11][CH2:12][CH:13]=[C:14]([CH3:21])[CH2:15][CH2:16][CH:17]=[C:18]([CH3:20])[CH3:19])=[CH:3][C:4]([NH:27][CH2:26][CH2:25][N:24]([CH3:28])[CH3:23])=[O:6]

参加物

3

反応物 2

HCID 66053N,N-DimethylethylenediamineHCID 1285703,7,11,15-Tetramethyl-2,6,10,14-hexadecatetraenic acid

生成物 1

HCID 53955451N-(3,7,11,15-Tetramethyl-2,6,10,14-hexadecatetraenoyl)-N',N'-dimethylethylenediamine収率 88%

実験手順

The procedure of Example 9 was repeated except that 6.1 g of 3,7,11,15-tetramethyl-2,6,10,14-hexadecatetraenoic acid and 3.3 ml of N,N-dimethylethylene diamine were used as starting materials. 6.5 g (yield 88%) of the title compound was obtained as a pale yellow oil.

出典と根拠

ORDレコード
ord-72725f58058848e5b39d0da2169d49e7
出典データセット
uspto-grants-1988_08
特許番号
US04762829

関連ノート

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