化工社化工社 化学情報印刷レポート · 研究参考用
Azobisisobutyronitrile → Methacrylic Acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Azobisisobutyronitrile | HCID 6547 | — |
| 反応物 | Methacrylate | HCID 87595 | — |
| 反応物 | Fluoro acrylate | HCID 21909953 | — |
| 溶媒 | Tetrahydrofuran | HCID 8028 | — |
| 生成物 | Methacrylic Acid | HCID 4093 | — |
| 生成物 | 2-Hydroxyethyl Methacrylate | HCID 13360 | — |
反応手順
This example illustrates conjoint use of the fluoro acrylate and methacrylate. 75.81 g (40.8 wt. %) of the perfluoroalkyl methacrylate (DuPont's Zonyl-TM), 72.3 g (38.9 wt. %) of the perfluoroalkyl acrylate (Hoechst-Celanese NUVA HF), 17.61 g (9.5 wt. %) of methacrylic acid, and 19.98 g (10.8 wt. %) of 2-hydroxyethyl methacrylate were polymerized in 300 ml THF, using 0.55 g AIBN as initiator, employing above-described procedure. Yield: 79.1%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05061769 |
| 出典データセット | uspto-grants-1991_10 |
| ORD ID | ord-cd1e6f295915444e88010f80a06c0170 |
| 出典メモ | uspto-grants-1991_10 |