化工社化工社 化学情報印刷レポート · 研究参考用
2-Cyclohexen-1-one → 1,3-Diethyl 2-(3-oxocyclohexyl)propanedioate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Cyclohexen-1-one | HCID 13594 | — |
| 反応物 | 2-(3-Oxo-4-propylcyclohexyl)-malonic acid diethyl ester | HCID 57487436 | — |
| 生成物 | 1,3-Diethyl 2-(3-oxocyclohexyl)propanedioate | HCID 317049 | 88% |
反応手順
Step 1 (3-Oxo-cyclohexyl)-malonic acid diethyl ester was prepared in 88% yield from cyclohexenone by the method described above for the synthesis of 2-(3-oxo-4-propyl-cyclohexyl)-malonic acid diethyl ester: 1H NMR (300 MHz, CDCl3) δ 4.44–4.12 (m, 4H), 2.88–1.22 (m, 16H).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07176242B2 |
| 出典データセット | uspto-grants-2007_02 |
| ORD ID | ord-051d527bec824cc8a072ae0b5466a09d |
| 出典メモ | uspto-grants-2007_02 |