化工社化工社 化学情報印刷レポート · 研究参考用
Diphenylamine → Triphenylamine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Diphenylamine | HCID 11487 | — |
| 反応物 | Iodobenzene | HCID 11575 | — |
| 反応物 | Potassium Hydroxide | HCID 14797 | — |
| 触媒 | Copper | HCID 23978 | — |
| 生成物 | Triphenylamine | HCID 11775 | 82% |
反応手順
The same equipment and conditions as in example I were employed with the following charge: 20.4 grams (0.1 mole) iodobenzene, 27.4 grams (0.15 mole) diphenylamine, 16.8 grams (0.3 mole) potassium hydroxide flakes, 15.0 grams of copper powder and 30.0 milliliters of Soltrol® 170. The above-identified product was obtained as colorless crystals having a melting point of 125°-126° C. Yield 82%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04764625 |
| 出典データセット | uspto-grants-1988_08 |
| ORD ID | ord-05bdd44fe3d447eaafc64f1cc325b326 |
| 出典メモ | uspto-grants-1988_08 |