化工社化工社 化学情報印刷レポート · 研究参考用
Dimethyl N-cyanodithioiminocarbonate → methyl N-cyano-1-methyl-2-(phenylmethylene)-hydrazinecarboximidothioate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dimethyl N-cyanodithioiminocarbonate | HCID 66289 | — |
| 反応物 | Benzaldehyde Methylhydrazone | HCID 302615 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 生成物 | methyl N-cyano-1-methyl-2-(phenylmethylene)-hydrazinecarboximidothioate | HCID 54323404 | — |
反応手順
A mixture of cyanocarbonimidodithioic acid dimethyl ester (1.46 g) and benzaldehyde N-methyl hydrazone (1.34 g) in acetonitrile was heated under reflux for 50 hr. The reaction mixture was cooled to 25° to give the title compound as colourless crystals, m.p. 132°-133° (0.73 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04764612 |
| 出典データセット | uspto-grants-1988_08 |
| ORD ID | ord-5a4c884a205c4c5d87920b320e7a65e5 |
| 出典メモ | uspto-grants-1988_08 |