化工社化工社 化学情報印刷レポート · 研究参考用
Methylhydrazine → N-cyano-1-methylhydrazinecarboximidothioic acid methyl ester
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methylhydrazine | HCID 6061 | — |
| 反応物 | Dimethyl N-cyanodithioiminocarbonate | HCID 66289 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 生成物 | N-cyano-1-methylhydrazinecarboximidothioic acid methyl ester | HCID 86738283 | — |
反応手順
A mixture of methyl hydrazine (0.48 ml) and cyanocarbonimidodithioic acid dimethyl ester (1.3 g) in acetonitrile was stirred at 25° for 16 hours. The resulting solution was evaporated to a gum which was crystallised from acetonitrile/ether to give the title compound as colourless granules (210 mg) m.p. 69°-71°.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04764612 |
| 出典データセット | uspto-grants-1988_08 |
| ORD ID | ord-3d31bfcbc0f843ba9ecffef034de6c02 |
| 出典メモ | uspto-grants-1988_08 |