Sodium ethoxide → ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6carboximidate

HRID 35157

反応式

HRID 35157 の反応式
[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16]#[N:17])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.[CH3:18][CH2:19][O-:20].[Na+]>C(O)C>[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16](=[NH:17])[O:20][CH2:19][CH3:18])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1

参加物

4

反応物 2

HCID 2723922Sodium ethoxideHCID 198338865,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile

生成物 1

HCID 19833914ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6carboximidate

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

starting from 5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile and sodium ethylate in ethanol there is obtained ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate and therefrom with hydrochloric acid in alcohol there is obtained the hydrochloride, m.p. 158° C. (with decomposition);

出典と根拠

ORDレコード
ord-ad64697779764f5296b06bd50992d95c
出典データセット
uspto-grants-1988_08
特許番号
US04766115

関連ノート

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