化工社化工社 化学情報印刷レポート · 研究参考用
5,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile → dodecyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 5,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile | HCID 19833886 | — |
| 反応物 | Sodium dodecane-1-thiolate | HCID 23672953 | — |
| 溶媒 | 1-Dodecanethiol | HCID 8195 | — |
| 生成物 | dodecyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate | HCID 19833911 | — |
反応手順
starting from 5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile and sodium dodecanethiolate in 1-dodecanethiol there is obtained dodecyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate, which is purified by flash chromatography on silica gel using n-hexane/ethyl acetate (1:1) as the eluent; 1H-NMR(CDCl3): 0.88 (t, CH3), 1.2-2.0 (20H), 2.5 (t, SCH2), 4.43 (s, 4H), 7.3-7.7 (8H);
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04766115 |
| 出典データセット | uspto-grants-1988_08 |
| ORD ID | ord-c0e9a35f334147d79dbd084f56ef54e6 |
| 出典メモ | uspto-grants-1988_08 |