関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Acetyl chloride | HCID 6367 | — |
| 反応物 | 2-Bromonaphthalene | HCID 11372 | — |
| 反応物 | Aluminum(III) Chloride | HCID 6451240 | — |
| 溶媒 | Nitrobenzene | HCID 7416 | — |
| 生成物 | 1-(6-Bromonaphthalen-2-yl)ethanone | HCID 12433082 | — |
反応手順
A mixture of 41.4 g of 2-bromonaphthalene, 15.7 g of acetyl chloride and 28 g of aluminum chloride in 250 ml of nitrobenzene was stirred at 100° C. for 4 hours. The reaction mixture was poured onto ice water and the resulting solid filtered off, washed with water and distilled under reduced pressure. The distillate was recrystallized from hexane to yield 2-bromo-6-acetylnaphthalene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04766127 |
|---|
| 出典データセット | uspto-grants-1988_08 |
|---|
| ORD ID | ord-6b8ce0e0912b4f5087e0b932e9425f44 |
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| 出典メモ | uspto-grants-1988_08 |
|---|
