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HRID 354523作成日:2026年10月23日

Phloroglucinol → Bisphenol P

https://huagongshe.com/ja/reaction/354523

反応式

関与物質

役割名称HCID仕込み量
反応物PhloroglucinolHCID 359—
反応物2,4-Dihydroxybenzoic AcidHCID 1491—
反応物1,1,1-Tris(4-hydroxyphenyl)ethaneHCID 93118—
反応物1,3,5-Tris(4-hydroxyphenyl)benzeneHCID 348148—
反応物Tri-(4-hydroxyphenyl)-phenyl methaneHCID 17820215—
反応物2-(4-Hydroxyphenyl)-2-(2,4-dihydroxyphenyl)-propaneHCID 21885520—
反応物4,6-Dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptaneHCID 21894433—
生成物Bisphenol PHCID 630355—

反応手順

The polycarbonates may, of course, be branched by incorporating small quantities of polyhydroxyl compounds, e.g. 0.05 to 2.0 mols percent (based on the quantity of bisphenols). Polycarbonates of this kind have been described, e.g. in German Offenlegungsschriften No. 1,570,533; 2,116,974 and 2,113,347, in British Patents No. 885,442 and 1,079,821 and in U.S. Pat. No. 3,544,514. The following are some of the polyhydroxyl compounds which are suitable for this purpose: Phloroglucinol, 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptene-(2), 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptane, 1,3,5-tri-(4-hydroxyphenyl)-benzene, 1,1,1-tri-(4-hydroxyphenyl)-ethane, tri-(4-hydroxyphenyl)-phenyl-methane, 2,2-bis-[4,4-(4,4'-dihydroxydiphenyl)-cyclohexyl]-propane, 2,4-bis-(4-hydroxyphenyl-4-isopropyl)-phenol,2,6-bis-(2'-hydroxy-5'-methyl-benzyl)-4-methylphenol, 2,4-dihydroxybenzoic acid, 2-(4-hydroxyphenyl)-2-(2,4-dihydroxyphenyl)-propane and 1,4-bis-(4',40"-dihydroxytriphenyl-methyl)-benzene.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号USRE031165
出典データセットuspto-grants-1983_03
ORD IDord-6ada6bb5c4e344879e79e1c331e424be
出典メモuspto-grants-1983_03