関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Phloroglucinol | HCID 359 | — |
| 反応物 | 2,4-Dihydroxybenzoic Acid | HCID 1491 | — |
| 反応物 | 1,1,1-Tris(4-hydroxyphenyl)ethane | HCID 93118 | — |
| 反応物 | 1,3,5-Tris(4-hydroxyphenyl)benzene | HCID 348148 | — |
| 反応物 | Tri-(4-hydroxyphenyl)-phenyl methane | HCID 17820215 | — |
| 反応物 | 2-(4-Hydroxyphenyl)-2-(2,4-dihydroxyphenyl)-propane | HCID 21885520 | — |
| 反応物 | 4,6-Dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptane | HCID 21894433 | — |
| 生成物 | Bisphenol P | HCID 630355 | — |
反応手順
The polycarbonates may, of course, be branched by incorporating small quantities of polyhydroxyl compounds, e.g. 0.05 to 2.0 mols percent (based on the quantity of bisphenols). Polycarbonates of this kind have been described, e.g. in German Offenlegungsschriften No. 1,570,533; 2,116,974 and 2,113,347, in British Patents No. 885,442 and 1,079,821 and in U.S. Pat. No. 3,544,514. The following are some of the polyhydroxyl compounds which are suitable for this purpose: Phloroglucinol, 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptene-(2), 4,6-dimethyl-2,4,6-tri-(4-hydroxyphenyl)-heptane, 1,3,5-tri-(4-hydroxyphenyl)-benzene, 1,1,1-tri-(4-hydroxyphenyl)-ethane, tri-(4-hydroxyphenyl)-phenyl-methane, 2,2-bis-[4,4-(4,4'-dihydroxydiphenyl)-cyclohexyl]-propane, 2,4-bis-(4-hydroxyphenyl-4-isopropyl)-phenol,2,6-bis-(2'-hydroxy-5'-methyl-benzyl)-4-methylphenol, 2,4-dihydroxybenzoic acid, 2-(4-hydroxyphenyl)-2-(2,4-dihydroxyphenyl)-propane and 1,4-bis-(4',40"-dihydroxytriphenyl-methyl)-benzene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 特許番号 | USRE031165 |
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| 出典データセット | uspto-grants-1983_03 |
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| ORD ID | ord-6ada6bb5c4e344879e79e1c331e424be |
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| 出典メモ | uspto-grants-1983_03 |
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