2-Methyl-3-buten-2-ol → 2,5-Dimethyl-2,5-hexanediol
反応式
[CH3:1][C:2]([OH:6])([CH:4]=[CH2:5])[CH3:3]>CC(O)C>[CH3:1][C:2]([OH:6])([CH2:5][CH2:4][C:2]([CH3:3])([OH:6])[CH3:1])[CH3:3]参加物
3
実験手順
2-Methyl-3-buten-2-ol, 2-propanol and tert.-butyl peroxy pivalate (75% solution in aliphates) are reacted in a molar ratio of 1:15:0.3 at 90° C. and a pressure of 500 kPa as described in example 1. After a contact period of 20 minutes of the reaction mixture in a tube reactor 95% of the olefin used has been converted. 2,5-dimethylhexane-2,5-diol is formed with a selectivity of 76%.
出典と根拠
- ORDレコード
- ord-eed7f6c0c9704090aaf4de213e18c8fa
- 出典データセット
- uspto-grants-1998_11
- 特許番号
- US05831134
反応ノート
読み込み中…