2-Methyl-3-buten-2-ol → 2,5-Dimethyl-2,5-hexanediol

HRID 355568

反応式

HRID 355568 の反応式
[CH3:1][C:2]([OH:6])([CH:4]=[CH2:5])[CH3:3]>CC(O)C>[CH3:1][C:2]([OH:6])([CH2:5][CH2:4][C:2]([CH3:3])([OH:6])[CH3:1])[CH3:3]

参加物

3

反応物 1

HCID 82572-Methyl-3-buten-2-ol

生成物 1

HCID 80312,5-Dimethyl-2,5-hexanediol

試薬・触媒・溶媒 1

HCID 3776Isopropanol溶媒

実験手順

2-Methyl-3-buten-2-ol, 2-propanol and tert.-butyl peroxy pivalate (75% solution in aliphates) are reacted in a molar ratio of 1:15:0.3 at 90° C. and a pressure of 500 kPa as described in example 1. After a contact period of 20 minutes of the reaction mixture in a tube reactor 95% of the olefin used has been converted. 2,5-dimethylhexane-2,5-diol is formed with a selectivity of 76%.

出典と根拠

ORDレコード
ord-eed7f6c0c9704090aaf4de213e18c8fa
出典データセット
uspto-grants-1998_11
特許番号
US05831134

関連ノート

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