化工社化工社 化学情報印刷レポート · 研究参考用
Methyl (4-nitrophenoxy)acetate → Methyl(4-aminophenoxy)acetate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methyl (4-nitrophenoxy)acetate | HCID 700522 | — |
| 触媒 | Palladium | HCID 23938 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | Methyl(4-aminophenoxy)acetate | HCID 6422115 | 97.6% |
反応手順
A procedure similar to that described in Example 6 was repeated, except that 30.8 g of methyl 4-nitro-phenoxyacetate (prepared as described in Preparation 36), 5.0 g of 10% w/w palladium-on-charcoal and 500 ml of methanol were used, to give 25.8 g of the title compound having Rf=0.79 (on silica gel thin layer chromatography using ethyl acetate as the developing solvent).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05834501 |
| 出典データセット | uspto-grants-1998_11 |
| ORD ID | ord-d75c053e7dda43a784c033be9ddf82c9 |
| 出典メモ | uspto-grants-1998_11 |