Ammonia → 4-Vinylbenzylamine (stabilized with MEHQ)
反応式
[CH:1]([CH:3](Cl)[C:4]1[CH:9]=CC=[CH:6][CH:5]=1)=C.[NH3:11].[Cl-].[NH4+].[CH:14](O)([CH3:16])[CH3:15]>>[NH2:11][CH2:15][C:14]1[CH:16]=[CH:9][C:4]([CH:3]=[CH2:1])=[CH:5][CH:6]=1参加物
5
実験手順
To a 250 mL flask was added vinylbenzyl chloride (7.63 g, 0.050 mol), concentrated aqueous ammonia (9.8 mL), and isopropanol (40 mL). The mixture was stirred for one week, at which point a large quantity of crystalline material (ammonium chloride) had precipitated. The solid was filtered off and washed with isopropanol. The mother liquor was evaporated on a rotary evaporator until no ammonia odor could be detected. Isopropanol (50 mL) was then added, and the mixture refrigerated for several hours. Following refrigeration, ammonium chloride which had precipitated was filtered off to yield 4-aminomethylstyrene which was used without further purification.
後処理
- customhad precipitated
- filtrationThe solid was filtered off
- washwashed with isopropanol
- customThe mother liquor was evaporated on a rotary evaporator until no ammonia odor
- additionIsopropanol (50 mL) was then added
- waitthe mixture refrigerated for several hours
- customhad precipitated
- filtrationwas filtered off
出典と根拠
- ORDレコード
- ord-ea73edb555474867b190288294f09fff
- 出典データセット
- uspto-grants-1998_11
- 特許番号
- US05840766
反応ノート
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