Ethanol → HCID 19600560、化合物
反応式
[CH3:1][C:2]1[C:7]([CH3:8])=[C:6]([O:9][CH2:10][CH2:11][N:12]2[C:16](=[O:17])[CH2:15][CH2:14][C:13]2=[O:18])[CH:5]=[CH:4][N+:3]=1[O-].C(O)C.[C:23]([O:26]C(=O)C)(=[O:25])[CH3:24]>>[C:23]([O:26][CH2:1][C:2]1[C:7]([CH3:8])=[C:6]([O:9][CH2:10][CH2:11][N:12]2[C:16](=[O:17])[CH2:15][CH2:14][C:13]2=[O:18])[CH:5]=[CH:4][N:3]=1)(=[O:25])[CH3:24]参加物
4
反応条件
- 温度
- 100 °C
実験手順
0.12 g of 2,3-dimethyl-4-(2-succinimidoethoxy)pyridine N-oxide was dissolved in 5 ml of acetic anhydride to obtain a solution. This solution was stirred at 100° C. for 0.5 hour and cooled, followed by the addition of 30 ml of ethanol. The obtained mixture was stirred at a room temperature for 0.5 hour and distilled to remove the solvent. Thus, 0.14 g of crude 2-acetoxymethyl-3-methyl-4-(2-succinimidoethoxy)pyridine was obtained as an oil.