(3-Bromopropyl)benzene → HCID 86753002、化合物
反応式
Br[CH2:2][CH2:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[S:11]([C:15]1[CH:21]=[CH:20][C:18]([CH3:19])=[CH:17][CH:16]=1)([O-:14])(=[O:13])=[S:12].[K+]>C(O)C>[C:5]1([CH2:4][CH2:3][CH2:2][O:14][S:11]([C:15]2[CH:21]=[CH:20][C:18]([CH3:19])=[CH:17][CH:16]=2)(=[S:12])=[O:13])[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1参加物
4
実験手順
The title compound was prepared as described in General Method 2 using 1-bromo-3-phenylpropane (0.044 mmol), potassium thiotosylate (0.044 mmol) and absolute ethanol (125 mL) to give an oil which was used without purification. 1H NMR (CDCl3) δ 1.95 (quint., 2 H), 2.459 (s, 3 H), 2.63 (t, 2 H), 2.95 (t, 2 H), 7.0-7.4 (m, 8 H), 7.7 (d, 2 H).
後処理
- customto give an oil which
- customwas used without purification
出典と根拠
- ORDレコード
- ord-f8d73daa2a704338a9e533a0f3acd15a
- 出典データセット
- uspto-grants-1998_11
- 特許番号
- US05840751
反応ノート
読み込み中…