Methylamine → HCID 178484896、化合物

HRID 358259ノート

反応式

HRID 358259 の反応式
[C:1]([NH:3][CH:4]=[N:5][C:6]1[CH:11]=[CH:10][C:9]([C:12]2[N:13]=[CH:14][NH:15][CH:16]=2)=[CH:8][CH:7]=1)#N.CN>O>[CH3:1][NH:3][CH:4]=[N:5][C:6]1[CH:11]=[CH:10][C:9]([C:12]2[N:13]=[CH:14][NH:15][CH:16]=2)=[CH:8][CH:7]=1

参加物

4

反応物 2

HCID 6329MethylamineHCID 178512241HCID 178512241、化合物

生成物 1

HCID 178484896HCID 178484896、化合物収率 70.9%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

Twenty grams of N-cyano-N'-[4-(imidazol-4-yl)-phenyl]-formamidine was added in one portion to 35% methylamine in water (70 ml). A few minutes after the addition, the solid N-methyl-N'-[4-(imidazol-4-yl)-phenyl]-formamidine separated out of the solution. This solid was collected by filtration, washed with water, and dried to yield 13.45 gm of the desired product, which was recrystallized from acetone.

後処理

  1. additionA few minutes after the addition
  2. customthe solid N-methyl-N'-[4-(imidazol-4-yl)-phenyl]-formamidine separated out of the solution
  3. filtrationThis solid was collected by filtration
  4. washwashed with water
  5. customdried

出典と根拠

ORDレコード
ord-d2f00d457ee1433c843a464d5043d005
出典データセット
uspto-grants-1984_08
特許番号
US04465841

反応ノート

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