関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Hydrogen Peroxide | HCID 784 | — |
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | 2-Propylpyridine | HCID 69320 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 生成物 | 2-Propylpyridine 1-oxide | HCID 88616 | — |
反応手順
20 ml of 2-n-propylpyridine were dissolved in 60 ml of glacial acetic acid, mixed with 40 ml of H2O2 (30%) and stirred for 16 hours at room temperature and 3 hours at 65° C. The acetic acid was then partly rotated out, the residue was adjusted to pH 8 with NaOH (20%), extracted with dichloromethane and the organic phase rotated in to dryness. 20 g of crude 2-propylpyridine-N-oxide were obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04997835 |
|---|
| 出典データセット | uspto-grants-1991_03 |
|---|
| ORD ID | ord-714f282edb704764ad9a8be82d432e6d |
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| 出典メモ | uspto-grants-1991_03 |
|---|
