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Tatb → 1,3,5-Trichloro-2,4,6-trinitrobenzene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Tatb | HCID 18286 | — |
| 反応物 | Thionyl Chloride | HCID 24386 | — |
| 反応物 | 1,3-Dichloro-5-methoxy-2,4,6-trinitrobenzene | HCID 14794057 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | 1,3,5-Trichloro-2,4,6-trinitrobenzene | HCID 17518 | — |
反応手順
Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) from 3,5-dichloroanisole. Nitration of 3,5-dichloroanisole under relatively mild conditions gave 3,5-dichloro-2,4,6-trinitroanisole in high yield and purity. Ammonolysis of this latter compound gave the desired TATB. Another route to TATB was through the treatment of the 3,5-dichloro-2,4,6-trinitroanisole with thionyl chloride and dimethylformamide to yield 1,3,5-trichloro-2,4,6-trinitrobenzene. Ammonolysis of this product produced TATB.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04997987 |
| 出典データセット | uspto-grants-1991_03 |
| ORD ID | ord-6e34c9a50fef40368a5c0a0a0abf8e7d |
| 出典メモ | uspto-grants-1991_03 |