化工社化工社 化学情報印刷レポート · 研究参考用
Ethanol → Ethyl 3,3-dimethylpent-4-enoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ethanol | HCID 702 | — |
| 反応物 | Phenol | HCID 996 | — |
| 反応物 | 1-(1,1-Diethoxyethoxy)-3-methylbut-2-ene | HCID 13321415 | — |
| 生成物 | Ethyl 3,3-dimethylpent-4-enoate | HCID 82262 | 72% |
反応手順
A mixture of 2.02 g of 1,1-diethoxy-1-(3-methyl-2-buten-1-yloxy)ethane and 20 mg of phenol was heated for 12 hours at 150°-160°, during which time ethanol was evolved. Distillation of the residue gave 1.12 g (72% yield) of ethyl 3,3-dimethyl-4-pentenoate, b.p. 80°-83°/57 mm.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04999451 |
| 出典データセット | uspto-grants-1991_03 |
| ORD ID | ord-6660faa2fb4841c8a261dc641d29db7d |
| 出典メモ | uspto-grants-1991_03 |