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Oxalyl chloride → 3-(Bromomethyl)benzoyl chloride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Oxalyl chloride | HCID 65578 | — |
| 反応物 | 3-(Bromomethyl)benzoic acid | HCID 245650 | — |
| 触媒 | Dimethylformamide | HCID 6228 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 3-(Bromomethyl)benzoyl chloride | HCID 14471076 | — |
反応手順
a solution of 12 g of m-bromomethylbenzoic acid 10.62 g of oxalyl chloride, 100 ml of dichloromethane and 5 drops of dimethylformamide was allowed to stand 48 hours and then evaporated. Hexane and ether were added, the mixture evaporated and the residue distilled on a Kugelroher, giving 12.5 g of m-bromomethylbenzoyl chloride as a yellow liquid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05411983 |
| 出典データセット | uspto-grants-1995_05 |
| ORD ID | ord-0166658b1735476e86d6c556d9f08893 |
| 出典メモ | uspto-grants-1995_05 |