Acetyl chloride → HCID 137226513、化合物

HRID 35962

反応式

HRID 35962 の反応式
[Cl:1][C:2](=[N:7][OH:8])[C:3]([Cl:6])=[N:4][OH:5].[C:9](Cl)(=[O:11])[CH3:10].C(N(CC)CC)C>ClC(Cl)C>[C:9]([OH:11])(=[O:5])[CH3:10].[C:9]([OH:11])(=[O:5])[CH3:10].[Cl:1][C:2](=[N:7][OH:8])[C:3]([Cl:6])=[N:4][OH:5]

参加物

5

反応物 3

HCID 6367Acetyl chlorideHCID 8471TriethylamineHCID 135527345Ethanediimidoyl dichloride, dihydroxy-

生成物 1

HCID 137226513HCID 137226513、化合物収率 30%

試薬・触媒・溶媒 1

HCID 63651,1-Dichloroethane溶媒

実験手順

The mixture of 2.0 g (0.0127 mol) of dichloroglyoxime (Compound No.6), 20 ml of dichloroethane and 2.4 g (0.0306 mol) of acetyl chloride was stirred in an ice bath. To the mixture, triethylamine (3.1 g, 0.0307 mol) was added dropwise, followed by stirring for 30 minutes. The reaction mixture was washed twice with 15 ml of water. The dichloroethane solution was concentrated under reduced pressure, to obtain white crystals of dichloroglyoxime diacetate (Compound No.2, yield: 30%).

後処理

  1. stirringby stirring for 30 minutes
  2. washThe reaction mixture was washed twice with 15 ml of water
  3. concentrationThe dichloroethane solution was concentrated under reduced pressure

出典と根拠

ORDレコード
ord-8cf7e900532942bd97b5cb69fa438ac1
出典データセット
uspto-grants-1995_05
特許番号
US05411990

関連ノート

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