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Acetyl chloride → HCID 137226513、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acetyl chloride | HCID 6367 | — |
| 反応物 | Triethylamine | HCID 8471 | — |
| 反応物 | Ethanediimidoyl dichloride, dihydroxy- | HCID 135527345 | — |
| 溶媒 | 1,1-Dichloroethane | HCID 6365 | — |
| 生成物 | HCID 137226513 | HCID 137226513 | 30% |
反応手順
The mixture of 2.0 g (0.0127 mol) of dichloroglyoxime (Compound No.6), 20 ml of dichloroethane and 2.4 g (0.0306 mol) of acetyl chloride was stirred in an ice bath. To the mixture, triethylamine (3.1 g, 0.0307 mol) was added dropwise, followed by stirring for 30 minutes. The reaction mixture was washed twice with 15 ml of water. The dichloroethane solution was concentrated under reduced pressure, to obtain white crystals of dichloroglyoxime diacetate (Compound No.2, yield: 30%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05411990 |
| 出典データセット | uspto-grants-1995_05 |
| ORD ID | ord-8cf7e900532942bd97b5cb69fa438ac1 |
| 出典メモ | uspto-grants-1995_05 |