Formic Acid → HCID 20063610、化合物

HRID 359641ノート

反応式

HRID 359641 の反応式
[NH2:1][C:2]1[C:7]([O:8][CH3:9])=[C:6]([N+:10]([O-:12])=[O:11])[C:5]([O:13][CH3:14])=[CH:4][C:3]=1[O:15][CH3:16].[CH:17](O)=[O:18]>O>[CH:17]([NH:1][C:2]1[C:7]([O:8][CH3:9])=[C:6]([N+:10]([O-:12])=[O:11])[C:5]([O:13][CH3:14])=[CH:4][C:3]=1[O:15][CH3:16])=[O:18]

参加物

4

反応物 2

HCID 284Formic AcidHCID 23009735HCID 23009735、化合物

生成物 1

HCID 20063610HCID 20063610、化合物

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

A mixture comprising 0.11 mole (26.6 g) of 2-amino-4-nitro-1,3,5-trimethoxybenzene and 55 ml of formic acid are refluxed during three hours. The reaction mixture is cooled and diluted with iced water. The expected product precipitates and is separated by filtration. After drying it is recrystallized from ethanol. It melts at 98° C.

後処理

  1. temperatureThe reaction mixture is cooled
  2. customThe expected product precipitates
  3. customis separated by filtration
  4. customAfter drying it
  5. customis recrystallized from ethanol

出典と根拠

ORDレコード
ord-29fa187fbf714e038a1767d6e11d47d9
出典データセット
uspto-grants-1991_03
特許番号
US05002585

反応ノート

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