Benzaldehyde → Hydrobenzamide
反応式
[NH4+:1].[OH-].[CH:3](=O)[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1>CC(O)C>[CH:7]1[CH:8]=[CH:9][C:4](/[CH:3]=[N:1]/[CH:3]([C:4]2[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=2)/[N:1]=[CH:3]/[C:4]2[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=2)=[CH:5][CH:6]=1参加物
4
実験手順
To a 3 L 3-necked flask equipped with a mechanical stirrer and a thermometer was added 1 L of concentrated NH4OH (ca 30%) (14.8 moles). A solution of benzaldehyde (265 g, 2.50 mol) in 500 mL of 2-propanol was added in one portion. The mixture was stirred vigorously at ca 22° C. for 43 hr. The resulting slurry was filtered and the filter cake was washed with water (1 L). After drying in vacuo, 242.4 g of hydrobenzamide was obtained as a white solid (mp 100°-102° C.) for a 97.4% yield.
後処理
- customTo a 3 L 3-necked flask equipped with a mechanical stirrer
- filtrationThe resulting slurry was filtered
- washthe filter cake was washed with water (1 L)
- customAfter drying in vacuo
出典と根拠
- ORDレコード
- ord-1782baef276b43558edf525bcf776e68
- 出典データセット
- uspto-grants-1995_05
- 特許番号
- US05412092
反応ノート
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