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Alumina → Methyl cyclohexanecarboxylate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Alumina | HCID 9989226 | — |
| 反応物 | Dimethyl Cyclohexane-1,1-dicarboxylate | HCID 10965525 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | Methyl cyclohexanecarboxylate | HCID 20748 | 316% |
反応手順
Per hour a solution of 4.5 g of dimethyl 1,1-cyclohexanedicarboxylate in 4.5 g of methanol was passed at 275° C. over 5 g of aluminum oxide. The exit mixture obtained over 6 hours (36.5 g) was distilled to yield 10.1 g of methyl cyclohexanecarboxylate (53%, based on diester used) and 7.7 g of the starting material.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05412120 |
| 出典データセット | uspto-grants-1995_05 |
| ORD ID | ord-2cbfd30ef447489789c90ee246ab483c |
| 出典メモ | uspto-grants-1995_05 |