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m-Chloroperbenzoic acid → HCID 178437532、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 反応物 | 2-ethyl-7-methyl-3H-Imidazo[4,5-b]pyridine | HCID 18693036 | — |
| 溶媒 | Chloroform | HCID 6212 | — |
| 生成物 | HCID 178437532 | HCID 178437532 | — |
反応手順
A solution of 2-ethyl-7-methylimidazo[4,5-b]pyridine (28 g, 174 mmol) and m-chloroperbenzoic acid (80-90%, 44.6 g) in CHCl3 (300 mL) was heated at reflux for 0.5 h. The mixture was concentrated and purified (SiO2, 100% CH2Cl2 gradient to 30% CH2Cl2 /MeOH) to afford 2-ethyl-7-methylimidazo[4,5-b]pyridine-4-oxide as a solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05412097 |
| 出典データセット | uspto-grants-1995_05 |
| ORD ID | ord-e67c5808e64140dd9c40efa9424f028d |
| 出典メモ | uspto-grants-1995_05 |