1,2-Diallyloxybenzene → 1,2-Diallyloxybenzene

HRID 361130ノート

反応式

HRID 361130 の反応式
C=CCOc1ccccc1OCC=C>CCOC(C)=O.O=C1CC[C@H]2CO[C@@H]1O2>C=CCc1ccc(CC=C)c(O)c1O.C=CCc1ccc(O)c(O)c1CC=C

参加物

7

反応物 1

HCID 778941,2-Diallyloxybenzene

生成物 3

HCID 778941,2-Diallyloxybenzene収率 56.391%HCID 131583253,4-Diallylbenzene-1,2-diol収率 16.325%HCID 132276783,6-Bis(prop-2-enyl)benzene-1,2-diol収率 19.926%

試薬・触媒・溶媒 3

HCID 8857Ethyl Acetate溶媒HCID 10975499(1S,5R)-6,8-Dioxabicyclo[3.2.1]octan-4-one溶媒HCID 7500Ethylbenzene内部標準

反応条件

温度
200 °C
その他
Reaction carried out in transient flow with ramps to vary the binary solvent composition, temperature and residence time. This reaction represents a single HPLC measurement sampled from within a transient flow ramp. Conditions are an estimate of what the reaction sample was exposed to prior to analysis.

後処理

  1. temperatureThe solution flowed through a customized cooling system made from an aluminum block and a Peltier assembly to quench the reaction.
  2. aliquotA Vici 4 port 2 position sampling valve sampled small aliquots (500 nL) into the HPLC for online analysis measurements of the reaction.

出典と根拠

ORDレコード
ord-cb1291d81f96484fb1a8590075b37a1e
出典データセット
Transient flow exploration of the effect of temperature, residence time and binary solvent ratios on a uni-molecular allyl substituted catechol reaction.
元リンク
出典を表示

反応ノート

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