関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Dimethylformamide | HCID 6228 | — |
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 反応物 | Benzenamine, N-propyl- | HCID 12153 | — |
| 反応物 | 2-Ethylhexyl bromide | HCID 86804 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | N-(2-ethylhexyl)-N-propylaniline | HCID 53707404 | 89% |
反応手順
A mixture of N-propylaniline (24 parts), 2-ethylhexyl bromide (58 parts), anhydrous potassium carbonate (42 parts) and dry N,N-dimethylformamide (50 parts) was stirred at 125° C. for 16 hours. The cooled reaction mixture was poured into water (250 parts), the organic phase separated and washed with water (2×200 parts) and dried at 90° C. and 15 mmHg to yield N-(2-ethylhexyl)-N-propylaniline (49 parts, 89%). Acetic anhydride was added to this to make a total of 69.5 parts.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05865857 |
|---|
| 出典データセット | uspto-grants-1999_02 |
|---|
| ORD ID | ord-e8c4b4af7a854ceba4a19e440aee6972 |
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| 出典メモ | uspto-grants-1999_02 |
|---|
