関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Aniline | HCID 6115 | — |
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 反応物 | 2-Ethylhexyl bromide | HCID 86804 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | N-(2-Ethylhexyl)aniline | HCID 61484 | 43% |
反応手順
A mixture of aniline (18.6 parts), 2-ethylhexyl bromide (42.4 parts), anhydrous potassium carbonate (30.3 parts) and dry N,N-dimethylformamide (100 parts) was stirred at 75° C. for 24 hours. The cooled mixture was filtered, diluted with dichloromethane and washed with 2N-hydrochloric acid (100 parts). The organic phase was evaported to leave oil which was triturated with petroleum ether and water to give N-(2-ethylhexyl)aniline (18 parts, 43%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05865857 |
|---|
| 出典データセット | uspto-grants-1999_02 |
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| ORD ID | ord-a1f10645be1845a384339f2e205461d5 |
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| 出典メモ | uspto-grants-1999_02 |
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