化工社化工社 化学情報印刷レポート · 研究参考用
N-heptylacetamide → 1-Heptanamine, N-ethyl-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | N-heptylacetamide | HCID 347488 | — |
| 反応物 | Aluminium lithium hydride | HCID 21226445 | — |
| 反応物 | Sodium hydroxide--water (1/1/1) | HCID 23719242 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | 1-Heptanamine, N-ethyl- | HCID 48038 | — |
反応手順
A mixture of a solution of 5.5 gms of the N-heptylacetamide in 150 ml of diethyl ether and 3.99 gms of lithium aluminum hydride are stirred at room temperature for 18 hours. The reaction mixture is then worked up with H2O/NaOH by the Fieser method, following which the organic layer is dried over MgSO4, filtered, and concentrated under vacuum to give N-heptyl-N-ethylamine.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05412137 |
| 出典データセット | uspto-grants-1995_05 |
| ORD ID | ord-f3528eb525984558858b648e2ac6c3f7 |
| 出典メモ | uspto-grants-1995_05 |