1-benzyl-4-[N-ethyl-N-(3-nitro-2-pyridinyl)amino]piperidine → 1-Benzyl-4-[N-ethyl-N-(3-amino-2-pyridinyl)amino]piperidine
反応式
[CH2:1]([N:8]1[CH2:13][CH2:12][CH:11]([N:14]([CH2:24][CH3:25])[C:15]2[C:20]([N+:21]([O-])=O)=[CH:19][CH:18]=[CH:17][N:16]=2)[CH2:10][CH2:9]1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C(N1CCC(N(CCC)C2C([N+]([O-])=O)=CC=CN=2)CC1)C1C=CC=CC=1>>[CH2:1]([N:8]1[CH2:13][CH2:12][CH:11]([N:14]([CH2:24][CH3:25])[C:15]2[C:20]([NH2:21])=[CH:19][CH:18]=[CH:17][N:16]=2)[CH2:10][CH2:9]1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1参加物
3
実験手順
Following the general procedure of EXAMPLE 204, Part B), and making non-critical variations but substituting 1-benzyl-4-[N-ethyl-N-(3-nitro-2-pyridinyl)amino]piperidine (EXAMPLE 204, Part A) for 1-benzyl-4-[N-propyl-N-(3-nitro-2-pyridinyl)amino]piperidine, the title compound is obtained, NMR (CDCl3) 7.84, 7.31, 7.26, 6.96, 6.85, 3.97, 3.50, 3.18, 3.07, 2.89, 2.02, 1.75 and 0.89δ.
出典と根拠
- ORDレコード
- ord-0befa284ee7440fcbbf735ad002d8353
- 出典データセット
- uspto-grants-1999_02