Tetraethylenepentamine → dodecylphenol TEPA

HRID 362763

反応式

HRID 362763 の反応式
[CH2:1]([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=1[OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].O1CCCOO1.[NH2:26][CH2:27][CH2:28][NH:29][CH2:30][CH2:31][NH:32][CH2:33][CH2:34][NH:35][CH2:36][CH2:37][NH2:38]>O>[CH2:1]([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=1[OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[NH2:38][CH2:37][CH2:36][NH:35][CH2:34][CH2:33][NH:32][CH2:31][CH2:30][NH:29][CH2:28][CH2:27][NH2:26]

参加物

5

反応物 3

HCID 8197TetraethylenepentamineHCID 1711442-DodecylphenolHCID 19593658CID 19593658

生成物 1

HCID 131721124dodecylphenol TEPA

試薬・触媒・溶媒 1

HCID 962Water溶媒3 回

実験手順

To a 2 liter 4-necked reaction flask equipped with a stirrer, Dean Stark trap, condenser and nitrogen sparger were charged dodecylphenol (524 g, 2.0 m), trioxane (60 g, 0.66 m) and tetraethylene pentamine (TEPA) (189 g, 1.0 m). The temperature was raised slowly to 110° C. at which time water evolution began. After 8 hours the temperature had risen to 115° C. and water evolution ceased (42 cc's of water were collected). The mixture was cooled and filtered to yield 730g of a dodecylphenol-TEPA product containing 9.1% nitrogen.

後処理

  1. customTo a 2 liter 4-necked reaction flask equipped with a stirrer
  2. customwere collected)
  3. temperatureThe mixture was cooled
  4. filtrationfiltered

出典と根拠

ORDレコード
ord-4f58afb3223547e1a8436c589d685f8c
出典データセット
uspto-grants-1999_02
特許番号
US05872082

関連ノート

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