化工社化工社 化学情報印刷レポート · 研究参考用
Sodium Carbonate → 5-Phenyl-2-picoline N-oxide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sodium Carbonate | HCID 10340 | — |
| 反応物 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 反応物 | 2-Methyl-5-phenylpyridine | HCID 76744 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 5-Phenyl-2-picoline N-oxide | HCID 14980528 | — |
反応手順
A solution of 3-phenyl-6-methyl pyridine (2.36 g, 13.95 mmol), in CH2Cl2 (40 mL) at 0° C. was treated with MCPBA (3.58 g, 13.95 mmol) for 1 hour. Saturated aq. Na2CO3 (50 mL) was added and the reaction was extracted with CH2Cl2 (20 mL). The organic extracts were dried (MgSO4), and the solvent evaporated in vacuo to afford the title compound.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05872136 |
| 出典データセット | uspto-grants-1999_02 |
| ORD ID | ord-05a8840426d74b2e8630c01407e52f00 |
| 出典メモ | uspto-grants-1999_02 |