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Chlorotrimethylsilane → Silane, trimethyl[[2-methyl-1-(1-methylethyl)-1-propenyl]oxy]-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Chlorotrimethylsilane | HCID 6397 | — |
| 反応物 | 2,4-Dimethyl-3-pentanone | HCID 11271 | — |
| 生成物 | Silane, trimethyl[[2-methyl-1-(1-methylethyl)-1-propenyl]oxy]- | HCID 11095327 | — |
反応手順
Reaction between 2,4-dimethyl-3-pentanone (1.2.4.3), trimethylsilyl chloride, and base gave 2,4-dimethyl-3-trimethysilyloxy-2-pentene (1.2.4.4) which was reacted with 1-fluoropyridinium triflate (1.2.4.5) to form 2,4-dimethyl-2-fluoro-3-pentanone (1.2.4.6). This product was reacted with (CH3)3S(O)+I- to form the title compound (1.2.4.2). ##STR31##
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05874573 |
| 出典データセット | uspto-grants-1999_02 |
| ORD ID | ord-12c500d629034589a9aeeb6f309ba54c |
| 出典メモ | uspto-grants-1999_02 |