関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Phenol | HCID 996 | — |
| 反応物 | Potassium Hydroxide | HCID 14797 | — |
| 反応物 | 2,2'-Bis(bromomethyl)-1,1'-biphenyl | HCID 251962 | — |
| 触媒 | Benzyl triethylammonium chloride | HCID 66133 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 2,2'-Bis(phenoxymethyl)biphenyl | HCID 53737607 | — |
反応手順
A mixture of 25.0 g (73.5 mmol) of 2,2'-bis(bromomethyl)biphenyl, 14.2 g (151 mmol) of phenol, 14.7 g (261 mmol) of pulverized potassium hydroxide and 3.41 g (15 mmol) of triethylbenzylammonium chloride is admixed with 120 ml of dichloromethane and stirred for 5 hours at 40° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05874642 |
|---|
| 出典データセット | uspto-grants-1999_02 |
|---|
| ORD ID | ord-9668b42c33fa4570bcfe893d5ace0f55 |
|---|
| 出典メモ | uspto-grants-1999_02 |
|---|
