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Potassium Carbonate → 1-(2-Hydrazinylethyl)pyrrolidine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | Hydrazine hydrate (1:1) | HCID 24654 | — |
| 反応物 | 1-(2-Chloroethyl)pyrrolidine hydrochloride | HCID 81668 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 1-(2-Hydrazinylethyl)pyrrolidine | HCID 3031556 | — |
反応手順
A mixture of 200 g of 85% hydrazine hydrate, 200 ml of water, 170 g of N-chloroethylpyrrolidine hydrochloride, and 70 g of potassium carbonate was boiled under reflux for seven hours. Sodium hydroxide (390 g) was added and the mixture was extracted with ether. The ethereal extract, dried and distilled, yielded the title compound, bp 107°-111° C. (18.5 mm).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04604390 |
| 出典データセット | uspto-grants-1986_08 |
| ORD ID | ord-16204511989e437e8028f0fb62d2c3b9 |
| 出典メモ | uspto-grants-1986_08 |