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Pyridine → Glycidyl benzoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Pyridine | HCID 1049 | — |
| 反応物 | Benzoyl chloride | HCID 7412 | — |
| 反応物 | Glycidol | HCID 11164 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | Glycidyl benzoate | HCID 25998 | 60% |
反応手順
A mixture containing 14.8 g (0.2 mole) of glycidol, 150 ml of anhydrous ether, 16 g (0.4 mole) of pyridine and 28 g (0.2 mole) of benzoyl chloride was stirred at room temperature for 2 hours. The mixture was filtered and the ether was evaporated to leave an oil. This oil was distilled to give 21 g (60%) of colorless oil: b.p. 92° C./0.5 mm Hg. The NMR and IR spectra were consistent with the assigned structure.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04604481 |
| 出典データセット | uspto-grants-1986_08 |
| ORD ID | ord-c63f62e849684cd993425acaf0a156f2 |
| 出典メモ | uspto-grants-1986_08 |