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Acetophenone → Ethyl 2-(2-Butyl)-3-hydroxy-3-methyl-3-phenylpropionate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acetophenone | HCID 7410 | — |
| 反応物 | Ethyl 3-methylpentanoate | HCID 560255 | — |
| 生成物 | Ethyl 2-(2-Butyl)-3-hydroxy-3-methyl-3-phenylpropionate | HCID 13742288 | 36% |
反応手順
The reaction of acetophenone (12 grams, 0.1 mole) with the enolate of ethyl 3-methylvalerate (14.4 grams, 0.1 mole) is carried out in the manner described in Example I. Distillation yields 9.5 grams (36%) of the pure product, b.p. 75°-80° C. (air bath temperature) at 0.05 mm Hg. I.R., N.M.R. and M.S. data confirm the above structure.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04607118 |
| 出典データセット | uspto-grants-1986_08 |
| ORD ID | ord-31bdf04c50534b1f8c9c6d14aa8d725e |
| 出典メモ | uspto-grants-1986_08 |