2-Naphthyl salicylate → 3-Hydroxybutanoic acid;3-hydroxypentanoic acid

HRID 365654

反応式

HRID 365654 の反応式
C1(P(=O)(O)O)CCCCC1.C1C=C2C(C=C([O:21][C:22]([C:24]3[C:29]([OH:30])=[CH:28][CH:27]=CC=3)=[O:23])C=C2)=CC=1>C([O-])(=O)CCCCCCCCCCCCCCCCC.[Zn+2].C([O-])(=O)CCCCCCCCCCCCCCCCC>[CH3:27][CH2:28][CH:29]([OH:30])[CH2:24][C:22]([OH:23])=[O:21].[CH3:28][CH:29]([OH:30])[CH2:24][C:22]([OH:23])=[O:21]

参加物

4

反応物 2

HCID 691822-Naphthyl salicylateHCID 70494Cyclohexylphosphonic acid

生成物 1

HCID 1078013-Hydroxybutanoic acid;3-hydroxypentanoic acid

試薬・触媒・溶媒 1

HCID 11178Zinc Stearate触媒

実験手順

PHA pellets were compounded from formulations based on BIOPOL powder of Mw=895k, 0.1 phr DZB (cyclohexylphosphonic acid), 0.4 phr ZnSt (zinc stearate) and 10 phr ATC plasticizer. Plasticizer were determined at 170 C and 5 kg load. The powder blends prepared in a Pappenmeier high speed blender were fed in a Betol single screw extruder, using the conditions summarized in Tables 1 and 4. BIOPOL, pellets with Mw of 727k were obtained with output from 3.0 kg/hr at a screw speed of 40 rpm. The following results were obtained:

後処理

  1. customThe powder blends prepared in a Pappenmeier high speed blender

出典と根拠

ORDレコード
ord-21687ea8772c45aea2e3c6895380df69
出典データセット
uspto-grants-2000_10
特許番号
US06127512

関連ノート

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