p-n-Octadecyloxybenzoic acid → 4-(trans-3-Decenyloxy)-benzoic acid

HRID 369538

反応式

HRID 369538 の反応式
C[O:2][C:3](=[O:21])[C:4]1[CH:9]=[CH:8][C:7]([O:10][CH2:11][CH2:12]/[CH:13]=[CH:14]/[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])=[CH:6][CH:5]=1.O.[OH-].[Li+].C(OC1C=CC(C(O)=O)=CC=1)CCCCCCCCCCCCCCCCC>CO>[CH2:11]([O:10][C:7]1[CH:6]=[CH:5][C:4]([C:3]([OH:21])=[O:2])=[CH:9][CH:8]=1)[CH2:12]/[CH:13]=[CH:14]/[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]

参加物

5

反応物 3

HCID 139993p-n-Octadecyloxybenzoic acidHCID 168937Lithium hydroxide, monohydrateHCID 18521096Methyl-4-(trans-3-decenyloxy)-benzoate

生成物 1

HCID 185211034-(trans-3-Decenyloxy)-benzoic acid

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

Ester 35h (600 mg, 2.07 mmol), and lithium hydroxide monohydrate (867 mg, 20.7 mmol) in 20 ml methanol were reacted according to the procedure for compound 36a. The yield was 500 mg (87%) of a white powder which was not quite pure (95%). The product was used without further purification.

後処理

  1. customThe product was used without further purification

出典と根拠

ORDレコード
ord-b213ca41cefd427f9bb23e37e0e5988d
出典データセット
uspto-grants-2000_10
特許番号
US06139771

関連ノート

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