Hydrochloric Acid → HCID 20273545、化合物

HRID 371255ノート

反応式

HRID 371255 の反応式
Cl.[CH2:2]([NH2:14])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].[P:15](Cl)([Cl:18])([Cl:17])=[O:16].Cl>>[CH2:2]([NH:14][P:15]([Cl:18])([Cl:17])=[O:16])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]

参加物

4

反応物 3

HCID 313Hydrochloric AcidHCID 24813Phosphorus oxychlorideHCID 458426Dodecylammonium chloride

生成物 1

HCID 20273545HCID 20273545、化合物

実験手順

n-Dodecylamine hydrochloride (44.4 g, 0.2 mol) and phosphorus oxychloride (91.4 mL, 1.0 mol) were reacted under nitrogen. A clear solution formed within 30 minutes, and the evolution of hydrogen chloride was observed. Heating at reflux was continued for 5 hours. Excess phosphorus oxychloride was removed by distillation in vacuum (40 to 5 torr, 24° to 50° C.) forming N-(n-dodecyl)phosphoramidic dichloride as a viscous liquid. The following spectroscopic data were obtained from the liquid:

後処理

  1. customA clear solution formed within 30 minutes
  2. temperatureHeating
  3. temperatureat reflux
  4. customExcess phosphorus oxychloride was removed by distillation in vacuum (40 to 5 torr, 24° to 50° C.)

出典と根拠

ORDレコード
ord-35b132f5a81341ba8d8faafe2642e027
出典データセット
uspto-grants-1985_07
特許番号
US04530714

反応ノート

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