化工社化工社 化学情報印刷レポート · 研究参考用
6-Methoxyquinoline → Quinoline, 1,2,3,4-tetrahydro-6-methoxy-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 6-Methoxyquinoline | HCID 14860 | — |
| 触媒 | Palladium | HCID 23938 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | Quinoline, 1,2,3,4-tetrahydro-6-methoxy- | HCID 67113 | 94.6% |
反応手順
6-Methoxyquinoline (1.00g) was dissolved in absolute ethanol (20 ml) and hydrogenated under pressure in the presence of 10% palladium on charcoal (0.10g) with shaking for about 40 hours. Filtration and evaporation to dryness of the filtrate gave 1,2,3,4-tetrahydro-6-methoxyquinoline as a light-brown gum (0.97g). The structure was supported by nmr spectrum.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04087561 |
| 出典データセット | uspto-grants-1978_05 |
| ORD ID | ord-1d27416b936e4f4b9c7fc294a512a2d7 |
| 出典メモ | uspto-grants-1978_05 |