反応式
[CH:1]1([C:6]([O:8]C)=O)[CH2:5][CH:4]=[CH:3][CH2:2]1.[O:10]1[CH2:15][CH2:14][CH2:13][CH2:12][CH:11]1[O:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22]Br>>[O:10]1[CH2:15][CH2:14][CH2:13][CH2:12][CH:11]1[O:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][C:1]1([CH2:6][OH:8])[CH2:2][CH:3]=[CH:4][CH2:5]1参加物
3
実験手順
The above procedure was repeated except that methyl cyclopent-3-ene carboxylate (prepared as described by A. H. Schmid and A. W. Wolkoff, J. Org. Chem. 32, 254 (1967)) was used with the 6-tetrahydropyranyloxyhexyl bromide of part D of this example and 1-(6-tetrahydropyranyloxyhexyl)-1-hydroxymethylcyclopent-3-ene was obtained as an oil (IR 3400, 3010 cm-1, nmr τ 4.4, 5.4, 6.35, 7.8, 8.5).
後処理
- customprepared
出典と根拠
- ORDレコード
- ord-5b7565c711c34383a61ba5d7a22531a1
- 出典データセット
- uspto-grants-1978_05
- 特許番号
- US04090019
関連ノート
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