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4-(Trifluoromethyl)aniline → 2,2'-Dithiobis[N-[4-(trifluoromethyl)phenyl]benzamide]
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 4-(Trifluoromethyl)aniline | HCID 9964 | — |
| 反応物 | 2,2'-Dithiodibenzoyl chloride | HCID 88164 | — |
| 溶媒 | Pyridine | HCID 1049 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 2,2'-Dithiobis[N-[4-(trifluoromethyl)phenyl]benzamide] | HCID 18935295 | 24.3% |
反応手順
This compound was prepared according to the general method of Example 77 using 2,2'-dithiobisbenzoyl chloride (1.12 g, 3.26 mmol) in 25 mL of dichloromethane and 4-aminobenzotrifluoride (1.05 g, 6.53 mmol) in 8 mL of pyridine. The crude product was recrystallized from water-DMF to yield 0.47 g of the title compound, mp 272°-275° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05734081 |
| 出典データセット | uspto-grants-1998_03 |
| ORD ID | ord-0f7687fce75f4342a1006eb952201a30 |
| 出典メモ | uspto-grants-1998_03 |