Acetaldehyde → 1-(3,3-Dimethyl-2-norbornyl)-2-propanone

HRID 372357

反応式

HRID 372357 の反応式
[CH:1]12[CH2:10][CH:7]([CH2:8][CH2:9]1)[C:5](=[CH2:6])[C:2]2([CH3:4])[CH3:3].[CH:11](=[O:13])[CH3:12].CC1C=CC(C)=CC=1C>>[CH3:3][C:2]1([CH3:4])[CH:1]2[CH2:10][CH:7]([CH2:8][CH2:9]2)[CH:5]1[CH2:6][C:11](=[O:13])[CH3:12]

参加物

4

反応物 3

HCID 177AcetaldehydeHCID 6616CampheneHCID 72471,2,4-Trimethylbenzene

生成物 1

HCID 203481821-(3,3-Dimethyl-2-norbornyl)-2-propanone収率 40.5%

実験手順

A 1 liter water jacketed photochemical reaction vessel equipped with magnetic stirrer and pyrex immersion well is charged with 418 g camphene (807, Aldrich) and 372 g acetaldehyde and 30 g diacetyl (photochemical hydrogen abstractor). The mixture is irradiated with a 450 medium pressure mercury lamp (Hanovia) for 55 hours, during which time five 30 g portions of diacetyl are added at varying intervals. The reaction mixture is combined with 150 g of 1,2,4-trimethyl benzene and washed with water. The material is distilled without fractionation and then redistilled through a 5' Vigreux column to yield 224 g colorless product, b.p. 70°-72° (55 mm Hg).

後処理

  1. customA 1 liter water jacketed photochemical reaction vessel equipped with magnetic stirrer
  2. additionare added
  3. washwashed with water
  4. distillationThe material is distilled without fractionation
  5. distillationredistilled through a 5' Vigreux column

出典と根拠

ORDレコード
ord-2e7d8fe2a5cf4907ac2feb9900b188a2
出典データセット
uspto-grants-1978_05
特許番号
US04090985

関連ノート

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