Ethanol → HCID 54021868、化合物

HRID 372686

反応式

HRID 372686 の反応式
[C:1]([CH2:4][S:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][C:16]([N:18]1[CH2:23][CH2:22][O:21][CH2:20][CH2:19]1)=[O:17])([OH:3])=[O:2].[CH2:24](O)[CH3:25].C1C2C(=CC=CC=2)C=CC=1S(O)(=O)=O>C1C=CC=CC=1>[C:1]([CH2:4][S:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][C:16]([N:18]1[CH2:19][CH2:20][O:21][CH2:22][CH2:23]1)=[O:17])([O:3][CH2:24][CH3:25])=[O:2]

参加物

5

反応物 3

HCID 702EthanolHCID 84202-Naphthalenesulfonic acidHCID 53921319HCID 53921319、化合物

生成物 1

HCID 54021868HCID 54021868、化合物

試薬・触媒・溶媒 1

HCID 241Benzene溶媒

実験手順

6 g (0.017 mole) of 11-(Carboxymethylthio)undecanoylmorpholine, 4.8 g (0.11 mole) of anhydrous ethyl alcohol and 1 g of 2-naphthalenesulfonic acid were placed in a flask equipped with reflux condenser, and refluxed for 16 hours. The mixture was dissolved in benzene, washed with water, dried over anhydrous sodium sulfate, filtered, passed through a column of activated alumina and stripped of solvent. The product, 11-(carbethoxymethylthio)undecanoylmorpholine, had a nitrogen content of 3.66% (theory, 3.75%).

後処理

  1. customequipped
  2. temperaturewith reflux condenser
  3. temperaturerefluxed for 16 hours
  4. washwashed with water
  5. dry with materialdried over anhydrous sodium sulfate
  6. filtrationfiltered

出典と根拠

ORDレコード
ord-0b7ac3f54d22409a845f7866c43f54ea
出典データセット
uspto-grants-1978_05
特許番号
US04092319

関連ノート

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