Sodium Methoxide → 2-Methoxy-5-phenylsulfinylpyridine
反応式
Br[C:2]1[CH:7]=[CH:6][C:5]([S:8]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[O:9])=[CH:4][N:3]=1.[CH3:16][O-:17].[Na+]>CO>[CH3:16][O:17][C:2]1[CH:7]=[CH:6][C:5]([S:8]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[O:9])=[CH:4][N:3]=1参加物
4
実験手順
A solution of 2-bromo-5-phenylsulfinylpyridine (2.82 g., 0.01 mole) and 0.50 g. of sodium methoxide is heated in 50 ml. of refluxing methanol for 5 hours. The reaction mixture is evaporated in vacuo, and the residue is diluted with water. The solids are collected by filtration, washed with water and dried to yield 2-methoxy-5-phenylsulfinylpyridine.
後処理
- customThe reaction mixture is evaporated in vacuo
- additionthe residue is diluted with water
- filtrationThe solids are collected by filtration
- washwashed with water
- customdried
出典と根拠
- ORDレコード
- ord-08450c8075fc4dc7bf677910a004504e
- 出典データセット
- uspto-grants-1978_05
- 特許番号
- US04092321
反応ノート
読み込み中…