Allylamine → 2,2,4-Trimethyl-1-allyl-1-aza-2-silacyclopentane

HRID 373344

反応式

HRID 373344 の反応式
Cl[Si:2]([CH3:9])([CH3:8])[CH2:3][CH:4]([CH3:7])[CH2:5]Cl.[CH2:10]([NH2:13])[CH:11]=[CH2:12]>>[CH3:8][Si:2]1([CH3:9])[CH2:3][CH:4]([CH3:7])[CH2:5][N:13]1[CH2:10][CH:11]=[CH2:12]

参加物

3

反応物 2

HCID 7853AllylamineHCID 86665Chloro(3-chloro-2-methylpropyl)dimethylsilane

生成物 1

HCID 191071842,2,4-Trimethyl-1-allyl-1-aza-2-silacyclopentane

実験手順

1,1,4-Trimethyl-2-allyl-2-aza-silacyclopentane was prepared. Chlorodimethyl(3-chloro-2-methylpropyl)silane (100 g, 0.54 mol) was slowly added to 211.73 g (3.71 mol, 6.87 eq) of undistilled allyl amine resulting in an exothermic reaction. This reaction mixture was stirred at room temperature for 15 hours, heated to reflux at atmospheric pressure for 72 hours, and heated to 120° C. under about 50 psig pressure for 16 hours. The following GC-MS ratios shown in Table I exemplified the reactions progression and the spectra observed were as shown.

後処理

  1. temperatureheated
  2. temperatureto reflux at atmospheric pressure for 72 hours
  3. temperatureheated to 120° C. under about 50 psig pressure for 16 hours

出典と根拠

ORDレコード
ord-898fd8da6c3440ab966d6e36af3519da
出典データセット
uspto-grants-1992_11
特許番号
US05162560

関連ノート

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