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Diethyl Carbonate → Diethylene glycol diethyl ether
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Diethyl Carbonate | HCID 7766 | — |
| 反応物 | Diethylene Glycol Monoethyl Ether | HCID 8146 | — |
| 反応物 | Aluminum | HCID 5359268 | — |
| 反応物 | Magnesium | HCID 5462224 | — |
| 生成物 | Diethylene glycol diethyl ether | HCID 8179 | — |
反応手順
Using the apparatus employed in Examples 15-27, a mixture of 2-(2-ethoxyethoxy)ethanol (1 mole) and diethyl carbonate (3 mole) was passed through 11.5 grams of a magnesium:aluminum mixed metal oxide (3/16 inch pellets, Mg/Al 3:1) at a temperature of 225° C. and at a liquid feed rate of 0.29 milliliters/minute. After a period of one hour, a total of 30.2 grams of liquid was collected. Analysis was performed by capillary gas chromatography (FID) using a DB-1701 column. The results were (area %) as follows:
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05164497 |
| 出典データセット | uspto-grants-1992_11 |
| ORD ID | ord-39a4d82ec2c74ebd8d3c66e62b4490c4 |
| 出典メモ | uspto-grants-1992_11 |