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Pyrrole → 21H,22H-Porphine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Pyrrole | HCID 8027 | — |
| 反応物 | Pentafluorobenzaldehyde | HCID 69558 | — |
| 反応物 | Tri(pentafluorophenyl)porphyrin | HCID 87642297 | — |
| 生成物 | 21H,22H-Porphine | HCID 137705241 | — |
反応手順
Compound C is subjected to a second Lindsey-type tri(pentafluorophenyl)porphyrin-ring construction with pentafluorobenzaldehyde and pyrrole, to give the Gable porphyrin, orthodi [mesotri(pentafluorophenyl)porphin]-benzene. In this step, Compound C is reacted again with pyrrole and pentafluorobenzaldehyde in a 1,4,3 molar ratio with BF3 0Et2 catalyst to give the desired ##STR5##
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05480986 |
| 出典データセット | uspto-grants-1996_01 |
| ORD ID | ord-69ca33a75c82441e9f07fe35dcfc1ae8 |
| 出典メモ | uspto-grants-1996_01 |